The game will be played at Stadio San Paolo on Wednesday, October 3 at 8pm BST.
The club has received an allocation of 2,639 tickets for fans to buy.
The club also received an additional allocation of 200 senior seats which, according to UEFA guidelines, will be used as part of the allocation of the players, players and staff of the UEFA Youth League team, the staff of the traveling club and the VIPs.
Napoli has instructed the club to write the name of each supporter who attends each ticket purchased.
The identification will be requested at the turnstiles when the stadium is accessed and compared with the name on the ticket.
Do not attempt to delete or change the name of the ticket as it will be denied entry.
We would also like to remind fans that important safety information will be provided for fans traveling to Naples in the run-up to the game.
The information has been provided by the Italian authorities together with the club officers of LFC, and we strongly recommend that you follow all the information and instructions given.
The draw on Thursday gave the French club Monaco an equally difficult task, with Atlético de Madrid, Borussia Dortmund and Club Brugge on the way.
Lyon, the third French club, will face Manchester City, Shakhtar Donetsk and Hoffenheim.
The holders of Real Madrid, who have won the competition for the last three years, are in Group G with Rome, CSKA Moscow and Viktoria Plzen.
Former Real Cristiano Ronaldo star, who proved the glory of the Champions League with Manchester United, will return to Old Trafford with his new club Juventus.
In what could be said is the less glamorous group, former European champion Porto will face Moscow’s Lokomotiv, Schalke 04 and Galatasaray.
Group E also has three former European champions: Bayern Munich, Benfica and Ajax Amsterdam, along with AEK Athens.
And for his return to the competition after an absence of six years, Inter Milan faced Barcelona, Tottenham Hotspur and PSV Eindhoven.
The draw in its entirety:
Group A: Atlético de Madrid, Borussia Dortmund, Monaco, Club de Brujas.
Group B: Barcelona, Tottenham, PSV Eindhoven, Inter Milan.
Group C: PSG, Napoli, Liverpool, Red Star Belgrade.
Group D: Lokomotiv Moscow, Porto, Schalke, Galatasaray.
Group E: Bayern Munich, Benfica, Ajax, AEK Athens.
Group F: Manchester City, Shakhtar Donetsk, Lyon, Hoffenheim.
Group G: Real Madrid, Rome, CSKA Moscow, Viktoria Plzen.
Group H: Juventus, Manchester United, Valencia, Young Boys.